K. Lund
U.S. Geological Survey, Mineral Resources, Faculty Member
... Although earlier workers thought these deposits were Cretaceous (Lindgren, 1904; Thompson and Ballard, 1924; Beckwith, 1928; Ross, 1931; Shenon and Reed, 1934), Anderson (1951) thought the Cretaceous plu-tons of the Idaho batholith... more
... Although earlier workers thought these deposits were Cretaceous (Lindgren, 1904; Thompson and Ballard, 1924; Beckwith, 1928; Ross, 1931; Shenon and Reed, 1934), Anderson (1951) thought the Cretaceous plu-tons of the Idaho batholith were the barren host rocks of ...
Research Interests:
ABSTRACT The Late Cretaceous Boulder batholith, southwestern MT, is composed of the Butte Granite and at least a dozen smaller granodiorite to syenogranite plutons. These plutons (81-73 Ma) were dated by zircon U-Pb geochronology using... more
ABSTRACT The Late Cretaceous Boulder batholith, southwestern MT, is composed of the Butte Granite and at least a dozen smaller granodiorite to syenogranite plutons. These plutons (81-73 Ma) were dated by zircon U-Pb geochronology using the SHRIMP. Typically for SIMS analysis of igneous zircon, the analytical spot is located midway between core and rim on an area that displays fine oscillatory zoning, thus sampling a ~25-30 µm area of vertically oriented zones to a depth of 1-2 µm. For this study, preliminary LA-ICP-MS analysis of Hf isotopes in zircons from several plutons suggested that some grains show significant variation (>5 εHf units) between inner and outer zones. This finding instigated a detailed investigation in which data for multiple isotopic systems (U-Pb, trace elements, O, and Hf ) were collected from horizontally oriented zones. Zircons were mounted in epoxy but not ground or polished. Reflected light, profilometer, and CL images were used to select homogeneous crystal faces. The outermost parts of 12-15 grains each from 12 plutons were analyzed consecutively for O and U-Pb isotope ratios, and trace element concentrations using an ion microprobe. The grains were then ground to half-thickness and O, U-Pb, and trace elements were measured at the centers of previously analyzed grains. The final step was Hf isotopic analysis by LA-ICP-MS which ablated a hole completely through the remaining half-grains. Although measurements of these isotopes from the outsides and insides of selected zircons is a limited form of depth-profiling, it enables acquisition of a very large, more precise data set than typical depth profiling. For all samples, U-Pb ages of zircon from interior and exterior zones are not resolvably different at ± 1% (2-sigma). However, in several samples a few outliers were identified, suggesting that interior parts in some grains formed later, during or after growth of the exterior parts of other grains. Thus, zircon growth was not an episodic process, but was semi-continuous, and probably controlled by inclusion in major rock-forming phases that isolated zircon from residual melt, local chemical gradients, and magma mixing. These processes are important for proper interpretation of isotopic and trace element data; the presumption that all zircon growth was initiated simultaneously could lead to misinterpretation of data arrays. Values of delta18O show variations between interior and exterior parts of grains both within a single sample and between samples. Hf isotopic data reveal that many grains in several samples are composed of two components that have resolvable differences in εHf suggesting multiple contributions to magmas. Trace element data suggest that some magmas followed systematic fractionation trends, whereas others were also influenced by magma mixing. Despite caveats pertaining to relative ages, analysis of trace elements and isotope ratios within discrete thin zones of individual zircons can be a powerful tool for understanding the details of magma evolution.
